ASSESSMENT OF SOLID MINERALS AND ELEMENTAL COMPOSITION OF ROCKS AND SOIL SAMPLES FROM SUKUR HILLS, MADAGALI, NIGERIA

Authors

  • Aliyu Benson
  • Ayodele Akinterinwa
  • Charles Milam
  • Humphrey M. Maina

Abstract

Mineral exploration is a critical component of any economy, and comprehensive geoscience data of a location provides critical information about the location's mineral exploration potential. This study evaluates the mineral composition of the rocks and soil samples from the area covering the Sukur Hill in Madagali, to provide geoscience insight of the area. Untapped rock and soil samples were obtained from five locations and labeled as follows: Sukur east rock (SER), Sukur north rock (SNR), Sukur south rock (SSR), Sukur center rock (SCR) and Sukur west rock (SWR), as well as Sukur east soil (SES), Sukur north soil (SNS), Sukur south soil (SSS), Sukur center soil (SCS) and Sukur west soil (SWS) respectively. X-ray diffraction (XRD) was used for the identification of solid minerals while X- ray florescence (XRF) was used for the analyses of the elemental oxides. Six minerals were found in the sample locations, according to the spectroscopic analysis. These include: albite, annite, kaolinite, microcline, orthoclase, and quartz. Quartz (36.6 - 100%) was recorded in all locations of the area, while annite (4%) and orthoclase (33%) were only recorded in SER and SCR respectively. The soil samples from the area shows the presence of albite, annite, kaolinite, microcline, montmorillonite, quartz, rutile, tremolite, zircon, phlogopite and calcite. The major and minor elemental oxides in rock samples studied follow the order SiO2 > Fe2O3 > Al2O3 > K2O > SO3 > CaO, and BaO > TiO2 > P2O5 > ZnO > MnO respectively, while the major and minor elemental oxides in soil samples follow the order SiO2 > Al2O3 > Fe2O3 > CaO > K2O > MgO > SO3, and P2O5 > TiO2 > BaO > Zr O2 > MnO > Rb2O, respectively. The elemental oxides recorded in this study compliments the minerals identified in the area. The overall results from this study makes valuable contributions to the mineral deposit assay of the area and this will provide handy information for future exploration.

Keywords: Elemental Oxides; Minerals; Rocks; Soil; XRD; XRF

Author Biographies

Aliyu Benson

1Department of Chemistry, Modibbo Adama University Yola, Nigeria.

Ayodele Akinterinwa

Department of Chemistry, Modibbo Adama University Yola, Nigeria.

Charles Milam

1Department of Chemistry, Modibbo Adama University Yola, Nigeria.

Humphrey M. Maina

1Department of Chemistry, Modibbo Adama University Yola, Nigeria.

 

 

Article DOI: DOI: https://doi.org/10.5281/zenodo.8411930

References

Fernandes WA. The Role of Mining in Economic Development in Namibia post-2008 Global Economic crisis. Doctoral dissertation, University of the Witwatersrand, Faculty of Engineering and the Built Environment, School of Mining Engineering. 2014: pp 4 -5.

Benson A, Maitera ON, & Osemeahon SA. Survey of solid minerals in rocks of Ditera and Waltadi, Song, Nigeria. Environment and Natural Resources Research, 2015: 5(4), 30.

Duarte IMR, Gomes CSF, & Pinho AB. Chemical weathering. In: Encyclopedia of engineering geology (Bobrowsky PT, Marker B. eds). Encyclopedia of Earth Sciences Series. Springer, Cham, 2018: pp 102 – 115.

Badmus BS, Olurin OT, Ganiyu SA, & Oduleye OT. Evaluation of Physical Parameters of various Solid Minerals within Southwestern Nigeria, using direct Experimental Laboratory Methods. American International Journal of Contemporary Research, 2013: 3(3) 152-161.

Naslund HR, & McBirney AR. Mechanisms of formation of Igneous Layering. In:

Developments in Petrology. Elsevier. 1996: 15, pp. 1-43.

Dolui G, Chatterjee S, & Chatterjee ND. Geophysical and Geochemical Alteration of Rocks in Granitic Profiles during Intense Weathering in Southern Purulia District, West Bengal, India. Modeling Earth Systems and Environment, 2016: 2(3), 132-137.

Alexander P, Maina HM, & Barminas JT. Quality of Solid Minerals in Rocks and Soils of Mubi South Local Government Area of Adamawa State, Nigeria. International Research Journal of Pure and Applied Chemistry, 2016: 10(4) 1-12.

Penuel BL, Maitera ON, Khan ME, & Ezekiel Y. X-Ray Diffraction Characterization of Sedimentary Rocks in Demsa Local Government Area of Adamawa State, Nigeria. Current Journal of Applied Science and Technology, 2017: 24(2), 1-9.

Obiefuna GI, Sini PH, & Maunde A. Geochemical and Mineralogical Composition of Granitic Rock Deposits of Michika Area NE Nigeria. International Journal of Scientific and Technology Research, 2018: 7(4), 160-170.

Tadzabia K, Maina HM, & Maitera ON, Milam C. Assessment of Mineral Oxides Composition in Rocks of Hong Local Government Area of Adamawa State, Nigeria. International Journal of Recent Innovations in Academic Research, 2019: 3(5), 230-235.

Dutrow B, & Clark M. Geochemical Instrumentation and Analysis. X-ray Powder Diffraction (XRD). Publicado por Science Education Resource Center at Carleton College. http://serc.carleton.edu. 2010.

Bunaciu AA, Udri Ş, Tioiu EG, & Aboul-Enein HY. X-ray diffraction: Instrumentation and Applications. Critical reviews in analytical chemistry, 2015: 45(4), 289-299.

Ali A, Chiang YW, & Santos RM. X-ray Diffraction Techniques for Mineral Characterization: A Review for Engineers of the Fundamentals, Applications, and Research Directions. Minerals, 2022: 12(2), 205.

Alexander P, Maina HM, Barminas JT, & Zira SP. Quality of Solid Minerals in the Rocks of Michika Local Government Area of Adamawa State, Nigeria. Journal of Sciences and Multidisplinary Research, 2011: 3, 23-26.

Benson A, Akinterinwa A, Osemeahon SA, & Ismaila A. Analyses of Minerals and Elemental Oxides in Rocks from Waltadi District, Song, Adamawa State Nigeria. Journal of Modern Chemistry and Chemical Technology, 2020: 11(2), 39 -50.

Wray RA, & Sauro F. An Updated Global Review of Solutional Weathering Processes and Forms in Quartz Sandstones and Quartzites. Earth-Science Reviews, 2017:171, 520-557.

Northam L, & Baranoski GVG. A Study on the Appearance of Quartz: Natural Phenomena Simulation group, University of Waterloo. Ontario, Canada N2L 3GI.Technical Report CS2008, 20.

Haldar SK, & Josip T. Basic mineralogy: Introduction to Mineralogy and Petrology, 2014: 338.

Malaza N, & Zhao B. Origin of Sodium and its Applications to Mine Water Remediation and Reduction in the South African Coal Mine Environment. Abstract of the International Mine Water Conference Proceedings. Produced by: Document Transformation Technologies, Pretoria, South Africa, 2009: 19-23.

Samantaray S. Physicochemical Characterization and Catalytic Application of Nanocomposite Oxides and Clay Based Nonaporous Materials for Synthesis of some Biologically Important Molecules. A PhD thesis submitted to the Department Chemistry, National Institute of Technology, Rourkela- 769008, Odisha.

Warr LN. IMA–CNMNC Approved Mineral Symbols. Mineralogical Magazine, 2021: 5(3), 291-320.

Bhattacharyya KG, & Gupta SS. Adsorption of a Few Heavy Metals on Natural and Modified Kaolinite and Montmorillonite: A Review. Advances in Colloid and Interface Science, 2008: 140(2), 114-131.

Hartwell JM. The Diverse uses of Montmorillonite. Clay minerals, 1965: 6, 11.

Dai Y. A Revised Checklist of Corticioid and Hydnoid Fungi in China for 2010. Mycoscience, 2011: 52(1) 69-79.

Kolenko YV, Burukhin AA, Churagulov BR, & Oleyni-kov NN. Material Letters, 2003: 57, 1124.

Kim HW, Kim HS, Na HG, Yang JC, Kim DY. Growth, Structural, Raman, and Photoluminescence Properties of Rutile TiO2 Nanowires Synthesized by the Simple Thermal Treatment. Journal of Alloys and Compounds, 2010: 504(1), 217-223.

Anthony EJ. Beach-ridge Development and Sediment Supply: Examples from West Africa. Marine Geology, 1995: 129(1-2), 175-186.

Rawat K, Sharma N, & Singh VK. X‐Ray Fluorescence and Comparison with Other Analytical Methods (AAS, ICP‐AES, LA‐ICP‐MS, IC, LIBS, SEM‐EDS, and XRD). X‐Ray Fluorescence in Biological Sciences: Principles, Instrumentation and Applications, 2022: 1-20.

Isaac E, Maitera ON, Donatus RB, Riki YE, Yerima EA, Tadzabia K, & Joseph B. Energy Dispersive X-Ray Fluorescence Determination of Minor and Major Elements in Soils of Mambilla Plateau Northeastern Nigeria. Journal of Environmental Chemistry and Ecotoxicology, 2019: 11(2), 22-28.

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Published

2023-10-05